A discrete hexagonal metallacycle decorated with multiple amide groups and long hydrophobic alkyl chains was constructed via [3+3] coordination-driven self-assembly, from which the ordered nanofibers and stimuli-responsive supramolecular gels were successfully obtained via hierarchical self-assembly.
N. Wu, L. Chen, C. Wang, Y. Ren, X. Li, L. Xu and H. Yang, Chem. Commun., 2014, 50, 4231 DOI: 10.1039/C3CC49054H
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