Issue 17, 2014
From the journal:

Chemical Communications

Formation, self-assembly and transformation of a transient selenotungstate building block into clusters, chains and macrocycles†

Jamie M. Cameron,‡a   Jing Gao,‡ab   Laia Vilà-Nadal,a   De-Liang Long*a  and  Leroy Cronin*a  

* Corresponding authors

a WestCHEM, School of Chemistry, The University of Glasgow, Glasgow, UK
E-mail: Deliang.Long@glasgow.ac.uk, Lee.Cronin@glasgow.ac.uk
Web: http://www.croninlab.com
Fax: +44 (0)141-330-4888
Tel: +44 (0)141-330-6650

b College of Chemical Engineering and Material Science, Zhejiang University of Technology, Chaowang Road 18, Hangzhou, Zhejiang 310014, China

Abstract

The one-pot syntheses of a series of dimeric and trimeric selenotungstates based on the [Se2W12O46]12− unit are presented alongside the structure of the tetrameric [Se8W48O176]32− wheel. Mass spectrometry has probed the stability of these clusters whilst their electronic structure has been contrasted to their known phosphotungstate analogues.

Graphical abstract: Formation, self-assembly and transformation of a transient selenotungstate building block into clusters, chains and macrocycles

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Article information

DOI
https://doi.org/10.1039/C3CC49293A
Article type
Communication
Submitted
06 Dec 2013
Accepted
03 Jan 2014
First published
06 Jan 2014

Chem. Commun., 2014,50, 2155-2157

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Formation, self-assembly and transformation of a transient selenotungstate building block into clusters, chains and macrocycles

J. M. Cameron, J. Gao, L. Vilà-Nadal, D. Long and L. Cronin, Chem. Commun., 2014, 50, 2155 DOI: 10.1039/C3CC49293A

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