Issue 23, 2014
From the journal:

Chemical Communications

A phthalocyanine–subphthalocyanine heterodinuclear dimer: comparison of spectroscopic properties with those of homodinuclear dimers of constituting units†

Norio Shibata,*a   Satoru Mori,a   Masamichi Hayashi,a   Masashi Umeda,a   Etsuko Tokunaga,a   Motoo Shiro,b   Hiroyasu Sato,b   Tomonori Hoshic  and  Nagao Kobayashi*d  

* Corresponding authors

a Department of Nanopharmaceutical Science and Department of Frontier Materials, Nagoya Institute of Technology, Gokiso, Showa-ku, Nagoya 466-8555, Japan
E-mail: nozshiba@nitech.ac.jp

b Rigaku Corporation, 3-9-12 Mastubara-cho, Akishima, Tokyo 196-8666, Japan

c Pharmaceutical Institute, Tohoku University, Sendai 980-8578, Japan

d Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan

Abstract

A phthalocyanine–subphthalocyanine heterodinuclear dimer has been disclosed for the first time with its unique flat-bowl-shaped structure revealed by X-ray crystallography. Its spectroscopic properties were compared with those of homodinuclear dimers of constituting units, as well as those of constituting monomeric units.

Graphical abstract: A phthalocyanine–subphthalocyanine heterodinuclear dimer: comparison of spectroscopic properties with those of homodinuclear dimers of constituting units

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Article information

DOI
https://doi.org/10.1039/C3CC49831J
Article type
Communication
Submitted
30 Dec 2013
Accepted
27 Jan 2014
First published
28 Jan 2014

Chem. Commun., 2014,50, 3040-3043

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A phthalocyanine–subphthalocyanine heterodinuclear dimer: comparison of spectroscopic properties with those of homodinuclear dimers of constituting units

N. Shibata, S. Mori, M. Hayashi, M. Umeda, E. Tokunaga, M. Shiro, H. Sato, T. Hoshi and N. Kobayashi, Chem. Commun., 2014, 50, 3040 DOI: 10.1039/C3CC49831J

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