The first Cu(I)-catalyzed cross-coupling reaction by hydrogen (H2) removal for the stereoselective synthesis of 3-phosphoindoles is reported. Going beyond the oxidative dehydrogenative coupling reactions reported recently, this reaction completely omits the oxidant and base, producing hydrogen (H2) as the only byproduct.
A. Zhou, L. Mao, G. Wang and S. Yang, Chem. Commun., 2014, 50, 8529 DOI: 10.1039/C4CC01815J
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