The efficient synthesis of functionalized enamines including β-enaminoesters was effectively accomplished by the direct condensation of functionalized sp3 carbanions such as acetates with formamides using in situ generated HMDS base from catalytic cesium fluoride and stoichiometric tristrimethylsilylamine.
H. Taneda, K. Inamoto and Y. Kondo, Chem. Commun., 2014, 50, 6523 DOI: 10.1039/C4CC02228A
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