Issue 63, 2014
From the journal:

Chemical Communications

Engineering chiral Fe(salen)-based metal–organic frameworks for asymmetric sulfide oxidation†

Zhiwei Yang,ab   Chengfeng Zhu,a   Zijian Li,a   Yan Liu,*a   Guohua Liub  and  Yong Cui*ac  

* Corresponding authors

a School of Chemistry and Chemical Technology and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, China
E-mail: liuy@sjtu.edu.cn, yongcui@sjtu.edu.cn
Fax: +86 21-5474-1297

b The Key Laboratory of Resource Chemistry of Ministry of Education, Shanghai Normal University, Shanghai 200234, China

c Collaborative Innovation Center of Chemical Science and Engineering, Tianjin 300072, China

Abstract

Two chiral porous Fe(salen)-based metal–organic frameworks are constructed and are shown to be efficient and recyclable heterogeneous catalysts for asymmetric oxidation of sulfides to sulfoxides with an enantioselectivity of up to 96%.

Graphical abstract: Engineering chiral Fe(salen)-based metal–organic frameworks for asymmetric sulfide oxidation

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Article information

DOI
https://doi.org/10.1039/C4CC03308F
Article type
Communication
Submitted
03 May 2014
Accepted
18 Jun 2014
First published
18 Jun 2014

Chem. Commun., 2014,50, 8775-8778

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Engineering chiral Fe(salen)-based metal–organic frameworks for asymmetric sulfide oxidation

Z. Yang, C. Zhu, Z. Li, Y. Liu, G. Liu and Y. Cui, Chem. Commun., 2014, 50, 8775 DOI: 10.1039/C4CC03308F

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