Allylic and benzylic alcohols can be selectively oxidized to their corresponding aldehydes or ketones in water containing nanoreactors composed of the designer surfactant TPGS-750-M. The oxidation relies on catalytic amounts of CuBr, bpy, and TEMPO, with N-methyl-imidazole; air is the stoichiometric oxidant.
B. H. Lipshutz, M. Hageman, J. C. Fennewald, R. Linstadt, E. Slack and K. Voigtritter, Chem. Commun., 2014, 50, 11378 DOI: 10.1039/C4CC05163G
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