A variety of functionalised imidazolidin-2-ones may be synthesised under very mild reaction conditions using non-toxic and cost-effective alkaline earth bis(amide) pre-catalysts in a 100% atom-efficient, intermolecular one-pot assembly from inexpensive alkyne and cumulene reagents.
M. Arrowsmith, W. M. S. Shepherd, M. S. Hill and G. Kociok-Köhn, Chem. Commun., 2014, 50, 12676 DOI: 10.1039/C4CC05223D
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