Issue 79, 2014
From the journal:

Chemical Communications

Preparation of highly substituted (β-acylamino)acrylates via iron-catalyzed alkoxycarbonylation of N-vinylacetamides with carbazates†

Ran Ding,a   Qiu-Chi Zhang,a   Yun-He Xu*a  and  Teck-Peng Loh*ab  

* Corresponding authors

a Hefei National Laboratory for Physical Sciences at the Microscale and Department of Chemistry, University of Science and Technology of China, Hefei, China
E-mail: xyh0709@ustc.edu.cn

b Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore, Singapore
E-mail: teckpeng@ntu.edu.sg

Abstract

An efficient iron(II)-catalyzed alkoxycarbonylation reaction between N-vinylacetamides and carbazates is reported. The corresponding useful highly substituted (β-acylamino)acrylates could be obtained in reasonable to good yields and stereoselectivity under mild reaction conditions.

Graphical abstract: Preparation of highly substituted (β-acylamino)acrylates via iron-catalyzed alkoxycarbonylation of N-vinylacetamides with carbazates

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Article information

DOI
https://doi.org/10.1039/C4CC05338A
Article type
Communication
Submitted
11 Jul 2014
Accepted
06 Aug 2014
First published
07 Aug 2014

Chem. Commun., 2014,50, 11661-11664

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Preparation of highly substituted (β-acylamino)acrylates via iron-catalyzed alkoxycarbonylation of N-vinylacetamides with carbazates

R. Ding, Q. Zhang, Y. Xu and T. Loh, Chem. Commun., 2014, 50, 11661 DOI: 10.1039/C4CC05338A

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