A combined CSD and ab initio study reveals that the interaction between the sp3 C-atom in para-substituted ArCF3 and electron rich atoms is weak (<5 kcal mol−1), somewhat directional, and thus comparable to CH–π interactions.
A. Bauzá, T. J. Mooibroek and A. Frontera, Chem. Commun., 2014, 50, 12626 DOI: 10.1039/C4CC05602G
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