Issue 80, 2014
From the journal:

Chemical Communications

An ultrastable {Ag55Mo6} nanocluster with a Ag-centered multishell structure†

Kun Zhou,a   Yun Geng,a   Li-Kai Yan,a   Xin-Long Wang,*a   Xian-Chun Liu,a   Guo-Gang Shan,a   Kui-Zhan Shao,a   Zhong-Min Su*a  and  Ying-Ning Yub  

* Corresponding authors

a Institute of Functional Material Chemistry, Key Lab of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, Jilin, China
E-mail: zmsu@nenu.edu.cn, wangxl824@nenu.edu.cn
Fax: +86 431-85684009
Tel: +86 431-85099108

b State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin, China

Abstract

An ultrastable [Ag55(MoO4)6]43+ ({Ag55Mo6} for short) nanocluster with a Ag-centered multishell structure in compound [Ag55(MoO4)6(C[triple bond, length as m-dash]CtBu)24(CH3COO)18](OAc)·2H2O (1) has been obtained. The ultrastability of 1 was demonstrated by Mulliken population analysis. In addition, the potential wide gap semiconductor property and electrochemical properties of 1 were investigated.

Graphical abstract: An ultrastable {Ag55Mo6} nanocluster with a Ag-centered multishell structure

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Article information

DOI
https://doi.org/10.1039/C4CC05893C
Article type
Communication
Submitted
29 Jul 2014
Accepted
13 Aug 2014
First published
13 Aug 2014

Chem. Commun., 2014,50, 11934-11937

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An ultrastable {Ag55Mo6} nanocluster with a Ag-centered multishell structure

K. Zhou, Y. Geng, L. Yan, X. Wang, X. Liu, G. Shan, K. Shao, Z. Su and Y. Yu, Chem. Commun., 2014, 50, 11934 DOI: 10.1039/C4CC05893C

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