This paper describes an enantioselective intermolecular allylic amination catalyzed by a chiral Brønsted acid via a possible chiral contact ion pair intermediate. A variety of symmetrical or unsymmetrical allylic alcohols can be smoothly aminated to afford the desired products in moderate to high yields with good enantioselectivities and/or regioselectivities.
M. Zhuang and H. Du, Org. Biomol. Chem., 2014, 12, 4590 DOI: 10.1039/C4OB00526K
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