Benzene derivatives are introduced into the dehydrogenative coupling via homolytic aromatic substitution (HAS) as arenes that couple with amides/ethers. NaOt-Bu is used as a critical promoter of HAS in combination with t-BuOOt-Bu as an oxidant.
R. Ueno and E. Shirakawa, Org. Biomol. Chem., 2014, 12, 7469 DOI: 10.1039/C4OB01253D
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