Issue 3, 2014

Highly efficient and practical resolution of 2,3:6,7-dibenzobicyclo[3.3.1]nona-2,6-diene-4,8-dione and stereoselective synthesis of its chiral diamine derivatives

Abstract

Highly efficient and practical resolution of 2,3:6,7-dibenzobicyclo[3.3.1]nona-2,6-diene-4,8-dione by inclusion complexation with commercially available enantiopure 1,1′-bi-2-naphthol is reported. The structure of the 1 : 1 inclusion complex of the diketone and BINOL was confirmed by single crystal X-ray crystallography.

Graphical abstract: Highly efficient and practical resolution of 2,3:6,7-dibenzobicyclo[3.3.1]nona-2,6-diene-4,8-dione and stereoselective synthesis of its chiral diamine derivatives

Supplementary files

Article information

Article type
Research Article
Submitted
14 Jan 2014
Accepted
10 Feb 2014
First published
26 Feb 2014

Org. Chem. Front., 2014,1, 271-274

Author version available

Highly efficient and practical resolution of 2,3:6,7-dibenzobicyclo[3.3.1]nona-2,6-diene-4,8-dione and stereoselective synthesis of its chiral diamine derivatives

B. Wang and Z. Gu, Org. Chem. Front., 2014, 1, 271 DOI: 10.1039/C4QO00011K

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