Titania particles modified with an extremely small amount (<0.01 mol%) of a rhodium species exhibited photocatalytic activity for the oxidative decomposition of acetaldehyde in air under visible-light irradiation. The reaction proceeded via a two-photon band-gap excitation mechanism resembling the Z-scheme with an external redox couple, using a built-in Rh(III)–Rh(IV) redox couple.
J. Kuncewicz and B. Ohtani, Chem. Commun., 2015, 51, 298 DOI: 10.1039/C4CC07049F
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