Issue 12, 2015
From the journal:

Chemical Communications

Assembly of tetrameric dimethyltin-functionalized selenotungstates: from nanoclusters to one-dimensional chains†

Wei-Chao Chen,a   Chao Qin,*a   Yang-Guang Li,a   Hong-Ying Zang,a   Kui-Zhan Shao,a   Zhong-Min Su,*a   En-Bo Wanga  and  Hong-Sheng Liu*b  

* Corresponding authors

a Institute of Functional Materials Chemistry Key Laboratory of Polyoxometalate Science of Ministry of Education Department of Chemistry, Northeast Normal University, Changchun 130024, P. R. China
E-mail: qinc703@nenu.edu.cn, zmsu@nenu.edu.cn

b School of Chemistry and Chemical Engineering, Daqing Normal University, Key Laboratory of Oilfield Applied chemistry, College of Heilongjiang Province, Daqing 163712, People's Republic of China
E-mail: hsliu899@126.com

Abstract

Two unprecedented tetrameric selenotungstates based on different Wells–Dawson-type fragments have been obtained: the {Sn7Se8W54} nanocluster exhibiting photocatalytic H2 evolution activity and the {Sn16Se11W56} chain, which are the first dimethyltin-functionalized selenotungstates reported and contain the unique {β-Se2W15} and {γ-Se2W14} building blocks, respectively.

Graphical abstract: Assembly of tetrameric dimethyltin-functionalized selenotungstates: from nanoclusters to one-dimensional chains

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Article information

DOI
https://doi.org/10.1039/C4CC08575B
Article type
Communication
Submitted
30 Oct 2014
Accepted
31 Dec 2014
First published
31 Dec 2014

Chem. Commun., 2015,51, 2433-2436

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Assembly of tetrameric dimethyltin-functionalized selenotungstates: from nanoclusters to one-dimensional chains

W. Chen, C. Qin, Y. Li, H. Zang, K. Shao, Z. Su, E. Wang and H. Liu, Chem. Commun., 2015, 51, 2433 DOI: 10.1039/C4CC08575B

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