Proton conduction in Mo(vi)-based metallo-supramolecular polymers†
Abstract
High proton conduction (8.5 × 10−2 mS cm−1) was observed in a Mo(VI)-based metallo-supramolecular polymer with carboxylic acids at 95%RH. The integration of OH groups into the polymer was analysed using FTIR spectroscopy and found to be crucial for the proton transport in the polymer.