Issue 2, 2015
From the journal:

Green Chemistry

Click chemistry mediated synthesis of bio-inspired phosphonyl-functionalized ionic liquids†

Richard A. Braun,a   Joseph L. Bradfield,a   Codey B. Henderson,b   Niloufar Mobarrez,‡a   Yinghong Sheng,a   Richard A. O'Brien,b   Alexandra C. Stenson,b   James H. Davis, Jr.b  and  Arsalan Mirjafari*a  

* Corresponding authors

a Department of Chemistry and Physics, Florida Gulf Coast University, Fort Myers, Florida 33965, USA
E-mail: amirjafari@fgcu.edu
Tel: +1-239-590-1270

b Department of Chemistry, University of South Alabama, Mobile, Alabama 36688, USA

Abstract

This study focuses on the synthesis of a class of novel biologically-inspired ionic liquids coupled with a phosphonate group containing short to long side chains (C3–C11) via the Pudovic reaction. The ionic liquids exhibited very low glass transition temperatures and were hydrophobic in character. This method has the attributes of “click” chemistry with outstanding efficiency, simplicity, yields and regioselectivity. The results of their calcium(II) ligating capability are also presented.

Graphical abstract: Click chemistry mediated synthesis of bio-inspired phosphonyl-functionalized ionic liquids

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Article information

DOI
https://doi.org/10.1039/C4GC01933D
Article type
Paper
Submitted
06 Oct 2014
Accepted
18 Nov 2014
First published
26 Nov 2014

Green Chem., 2015,17, 1259-1268

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Click chemistry mediated synthesis of bio-inspired phosphonyl-functionalized ionic liquids

R. A. Braun, J. L. Bradfield, C. B. Henderson, N. Mobarrez, Y. Sheng, R. A. O'Brien, A. C. Stenson, J. H. Davis and A. Mirjafari, Green Chem., 2015, 17, 1259 DOI: 10.1039/C4GC01933D

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