A catalytic metal-free hydrogenation of naphthylamines using B(C6F5)3 as a catalyst was successfully achieved under mild conditions for the first time to furnish a variety of tetrahydronaphthylamines in 88–99% yields.
G. Li, Y. Liu and H. Du, Org. Biomol. Chem., 2015, 13, 2875 DOI: 10.1039/C5OB00009B
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