Herein, we report a fast (15 min) and solvent-free mechanochemical approach to construct polymers of intrinsic microporosity (PIMs) with high molecular mass and low polydispersity by solid grinding. The enhanced reaction efficiency results from the instantaneous frictional heating and continuous exposure of active sites within those solid reactants.
P. Zhang, X. Jiang, S. Wan and S. Dai, J. Mater. Chem. A, 2015, 3, 6739 DOI: 10.1039/C4TA07196D
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