The possibility of controlling magnetic anisotropy by tuning contribution of second order perturbation to spin–orbit coupling through modulation of the coordination environment is investigated. Subtle variation of the coordination environment triggers a remarkable deviation in the axial zero field splitting parameter of seven coordinate Co(II) complexes.
M. Dey, S. Dutta, B. Sarma, R. Ch. Deka and N. Gogoi, Chem. Commun., 2016, 52, 753 DOI: 10.1039/C5CC07397A
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