Issue 85, 2016

Bimetallic MOFs (H3O)x[Cu(MF6)(pyrazine)2]·(4 − x)H2O (M = V4+, x = 0; M = Ga3+, x = 1): co-existence of ordered and disordered quantum spins in the V4+ system

Abstract

The title compounds are bimetallic MOFs containing [Cu(pyz)2]2+ square lattices linked by MF6n octahedra. In each, only the Cu2+ spins exhibit long-range magnetic order below 3.5 K (M = V4+) and 2.6 K (M = Ga3+). The V4+ spins remain disordered down to 0.5 K.

Graphical abstract: Bimetallic MOFs (H3O)x[Cu(MF6)(pyrazine)2]·(4 − x)H2O (M = V4+, x = 0; M = Ga3+, x = 1): co-existence of ordered and disordered quantum spins in the V4+ system

Supplementary files

Article information

Article type
Communication
Submitted
26 Jul 2016
Accepted
27 Sep 2016
First published
27 Sep 2016

Chem. Commun., 2016,52, 12653-12656

Bimetallic MOFs (H3O)x[Cu(MF6)(pyrazine)2]·(4 − x)H2O (M = V4+, x = 0; M = Ga3+, x = 1): co-existence of ordered and disordered quantum spins in the V4+ system

J. L. Manson, J. A. Schlueter, K. E. Garrett, P. A. Goddard, T. Lancaster, J. S. Möller, S. J. Blundell, A. J. Steele, I. Franke, F. L. Pratt, J. Singleton, J. Bendix, S. H. Lapidus, M. Uhlarz, O. Ayala-Valenzuela, R. D. McDonald, M. Gurak and C. Baines, Chem. Commun., 2016, 52, 12653 DOI: 10.1039/C6CC05873F

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