Issue 83, 2016
From the journal:

Chemical Communications

Synthesis and solid state structure of a metalloid tin cluster [Sn10(trip8)]†

J. Wiederkehr,a   C. Wölpera  and  S. Schulz ORCID logo *a  

* Corresponding authors

a Faculty of Chemistry, Inorganic Chemistry, University of Duisburg-Essen, Universitätsstr. 5-7, S07S03C30, 45114 Essen, Germany
E-mail: stephan.schulz@uni-due.de
Fax: +49-201-1833830
Tel: +49-201-1834635

Abstract

(trip2Sn)2 (trip = 2,4,6-i-Pr3C6H2) reacts with Mg(I) reductants (LMg)2 (L = HC[C(Me)N(dipp)]2) and (L′Mg)2 (L′ = HC[C(Me)N(mes)]2) with Sn–C bond cleavage and formation of the novel metalloid tin cluster Sn10trip8 1 or elemental tin. 1, which contains Sn atoms in the formal oxidation states 0, +I and +II, and the side products LMgtrip (2) and L′Mgtrip (3) were characterized spectroscopically and by single crystal X-ray diffraction.

Graphical abstract: Synthesis and solid state structure of a metalloid tin cluster [Sn10(trip8)]

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Article information

DOI
https://doi.org/10.1039/C6CC06770K
Article type
Communication
Submitted
17 Aug 2016
Accepted
25 Aug 2016
First published
25 Aug 2016
This article is Open Access
Creative Commons BY license

Chem. Commun., 2016,52, 12282-12285

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Synthesis and solid state structure of a metalloid tin cluster [Sn10(trip8)]

J. Wiederkehr, C. Wölper and S. Schulz, Chem. Commun., 2016, 52, 12282 DOI: 10.1039/C6CC06770K

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