Magnesium hydridotriphenylborate [Mg(thf)6][HBPh3]2: a versatile hydroboration catalyst

Debabrata Mukherjee; Satoru Shirase; Thomas P. Spaniol; Kazushi Mashima; Jun Okuda

doi:10.1039/C6CC06805G

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Magnesium hydridotriphenylborate [Mg(thf)₆][HBPh₃]₂: a versatile hydroboration catalyst†

Debabrata Mukherjee,^a Satoru Shirase,^b Thomas P. Spaniol,^a Kazushi Mashima^b and Jun Okuda

*^a

Author affiliations

* Corresponding authors

^a Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, Aachen, Germany
E-mail: jun.okuda@ac.rwth-aachen.de

^b Graduate School of Engineering Science, Osaka University, Toyonaka, Osaka 560-8531, Japan

Abstract

Magnesium bis(hydridotriphenylborate), isolated as a solvent-separated ion pair [Mg(thf)₆][HBPh₃]₂, effectively catalyzed the hydroboration of several unsaturated substrates including CO₂.

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Article information

DOI: https://doi.org/10.1039/C6CC06805G
Article type: Communication
Submitted: 18 Aug 2016
Accepted: 12 Oct 2016
First published: 13 Oct 2016

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Chem. Commun., 2016,52, 13155-13158

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Magnesium hydridotriphenylborate [Mg(thf)₆][HBPh₃]₂: a versatile hydroboration catalyst

D. Mukherjee, S. Shirase, T. P. Spaniol, K. Mashima and J. Okuda, Chem. Commun., 2016, 52, 13155 DOI: 10.1039/C6CC06805G

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