Issue 94, 2016
From the journal:

Chemical Communications

Rational design of a flu-type heterometallic cluster-based Zr-MOF†

Yan-Xi Tan,a   Xue Yang,ab   Bei-Bei Liab  and  Daqiang Yuan ORCID logo *a  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, China
E-mail: ydq@fjirsm.ac.cn

b University of the Chinese Academy of Sciences, Beijing, China

Abstract

Following the HSAB principle, the cooperative assembly of tetrahedral [Cu4I4(Ina)4]4− metalloligands and 8-connecting [Zr6(μ3-OH)8(OH)8]8+ building units leads to the first heterometallic cluster-based Zr-MOF (1). The results provide a successful strategy for rational design of heterometallic cluster-based Zr-MOFs.

Graphical abstract: Rational design of a flu-type heterometallic cluster-based Zr-MOF

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Article information

DOI
https://doi.org/10.1039/C6CC08191F
Article type
Communication
Submitted
11 Oct 2016
Accepted
26 Oct 2016
First published
26 Oct 2016

Chem. Commun., 2016,52, 13671-13674

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Rational design of a flu-type heterometallic cluster-based Zr-MOF

Y. Tan, X. Yang, B. Li and D. Yuan, Chem. Commun., 2016, 52, 13671 DOI: 10.1039/C6CC08191F

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