Heterodimers of heterometallic rings

Grigore Timco; Simone Marocchi; Elena Garlatti; Claire Barker; Morten Albring; Valerio Bellini; Franca Manghi; Eric J. L. McInnes; Robin G. Pritchard; Floriana Tuna; Wolfgang Wernsdorfer; Giulia Lorusso; Giuseppe Amoretti; Stefano Carretta; Marco Affronte; Richard E. P. Winpenny

doi:10.1039/C6DT01941B

Heterodimers of heterometallic rings†

Grigore Timco,^a Simone Marocchi,^bc Elena Garlatti,^d Claire Barker,^a Morten Albring,^a Valerio Bellini,^c Franca Manghi,^bc Eric J. L. McInnes,^a Robin G. Pritchard,^a Floriana Tuna,^a Wolfgang Wernsdorfer,^e Giulia Lorusso,‡^bc Giuseppe Amoretti,^d Stefano Carretta,^d Marco Affronte*^bc and Richard E. P. Winpenny*^a

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* Corresponding authors

^a School of Chemistry and Photon Science Institute, The University of Manchester, Oxford Road. M13 9PL, Manchester, UK
E-mail: richard.winpenny@manchester.ac.uk
Fax: +(44) 0 161-275-4616

^b Dipartimento di Scienze Fisiche, Informatiche e Matematiche, Università di Modena e Reggio Emilia, via Campi 213/a, 41125 Modena, Italy

^c CNR-NANO-S3 via Campi 213/a, 41100 Modena, Italy

^d Dipartimento di Fisica e Scienze della Terra, Università di Parma, Parco Area delle Scienze 7/A, 43124 Parma, Italy

^e Laboratoire Louis Néel – CNRS, BP 166, 25 Avenue des Martyrs, 38042 GRENOBLE Cedex 9, France

Abstract

Nine new complexes are reported involving linked heterometallic rings; one ring is designed as a ligand for the second, and the compounds produced can be regarded as molecular prototypes for implementing quantum gates featuring two subtly different qubits.

This article is part of the themed collections: Celebrating our 2019 Prize and Award winners and Molecular Spintronics : The role of Coordination Chemistry

Dalton Transactions

Heterodimers of heterometallic rings†

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