Issue 4, 2016

Transition-metal-free regioselective synthesis of alkylboronates from arylacetylenes and vinyl arenes

Abstract

A transition-metal-free synthesis of alkylboronates, utilizing arylacetylenes or vinyl arenes and bis(pinacolato)diboron through tandem borylation and protodeboronation, has been developed. This reaction is efficient, practical and environmentally benign, leading to anti-Markovnikov products with excellent regioselectivity, broad functional group tolerance and excellent yields in both small and gram scales.

Graphical abstract: Transition-metal-free regioselective synthesis of alkylboronates from arylacetylenes and vinyl arenes

Supplementary files

Article information

Article type
Communication
Submitted
03 Nov 2015
Accepted
22 Dec 2015
First published
06 Jan 2016

Green Chem., 2016,18, 932-936

Transition-metal-free regioselective synthesis of alkylboronates from arylacetylenes and vinyl arenes

K. Yang and Q. Song, Green Chem., 2016, 18, 932 DOI: 10.1039/C5GC02633D

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