A triptycene-based porous hydrogen-bonded organic framework for guest incorporation with tailored fitting

Wenqing Yan; Xiaopeng Yu; Tao Yan; Doufeng Wu; Erlong Ning; Yi Qi; Ying-Feng Han; Qiaowei Li

doi:10.1039/C7CC00557A

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A triptycene-based porous hydrogen-bonded organic framework for guest incorporation with tailored fitting†

Wenqing Yan,^a Xiaopeng Yu,^a Tao Yan,^a Doufeng Wu,^a Erlong Ning,^a Yi Qi,^a Ying-Feng Han*^ab and Qiaowei Li

*^a

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* Corresponding authors

^a Department of Chemistry and iChEM (Collaborative Innovation Center of Chemistry for Energy Materials), Fudan University, Shanghai 200433, P. R. China
E-mail: qwli@fudan.edu.cn

^b Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an 710069, P. R. China
E-mail: yfhan@nwu.edu.cn

Abstract

A hydrogen-bonded organic framework (HOF) was constructed by avoiding potential π–π stacking of building blocks with robust and non-coplanar triptycene-based modules. The tailored-fitting interactions were demonstrated by the adsorption of fullerene with a concentration enrichment of ∼420 times in the pores.

This article is part of the themed collection: Most downloaded articles of 2017: Inorganic and Materials Chemistry

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Article information

DOI: https://doi.org/10.1039/C7CC00557A
Article type: Communication
Submitted: 20 Jan 2017
Accepted: 27 Feb 2017
First published: 28 Feb 2017

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Chem. Commun., 2017,53, 3677-3680

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A triptycene-based porous hydrogen-bonded organic framework for guest incorporation with tailored fitting

W. Yan, X. Yu, T. Yan, D. Wu, E. Ning, Y. Qi, Y. Han and Q. Li, Chem. Commun., 2017, 53, 3677 DOI: 10.1039/C7CC00557A

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Chemical Communications

A triptycene-based porous hydrogen-bonded organic framework for guest incorporation with tailored fitting†

Abstract

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A triptycene-based porous hydrogen-bonded organic framework for guest incorporation with tailored fitting

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