Issue 65, 2017

Surface-assisted dehydrogenative homocoupling and cyclodehydrogenation of mesityl groups on a copper surface

Abstract

We present for the first time an adjacent dehydrogenative homocoupling and cyclodehydrogenation reaction of mesityl groups to form a synthetic nanoribbon on Cu(110). Submolecular resolution scanning tunneling microscopy (STM) observations and density functional theory (DFT) calculations confirm the formation of an ethylene (–CH[double bond, length as m-dash]CH–) unit or an aromatic six-membered ring group.

Graphical abstract: Surface-assisted dehydrogenative homocoupling and cyclodehydrogenation of mesityl groups on a copper surface

Supplementary files

Article information

Article type
Communication
Submitted
22 May 2017
Accepted
26 Jul 2017
First published
26 Jul 2017

Chem. Commun., 2017,53, 9151-9154

Surface-assisted dehydrogenative homocoupling and cyclodehydrogenation of mesityl groups on a copper surface

X. Leng, Y. Lu, G. Feng, Z. Wang, W. Li, X. Liu, R. Zhang, N. Zhang and L. Wang, Chem. Commun., 2017, 53, 9151 DOI: 10.1039/C7CC03950F

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