Issue 1, 2017
From the journal:

Dalton Transactions

Synthesis, crystal structure and magnetic properties of a cyanide-bridged heterometallic {CoIIMnIII} chain†

Maria-Gabriela Alexandru,*a   Diana Visinescu,b   Sergiu Shova,c   Francesc Lloretd  and  Miguel Julve*d  

* Corresponding authors

a Department of Inorganic Chemistry, Physical Chemistry and Electrochemistry, Faculty of Applied Chemistry and Materials Science, University Politehnica of Bucharest, 1-7 Gh. Polizu Street, Bucharest, Romania
E-mail: alexandru.gabriela@gmail.com

b Coordination and Supramolecular Chemistry Laboratory, “Ilie Murgulescu” Institute of Physical Chemistry, Romanian Academy, Splaiul Independentei 202, Bucharest-060021, Romania

c “Petru Poni” Institute of Macromolecular Chemistry of the Romanian Academy, Aleea Grigore Ghica Vodă 41-A, RO-700487 Iasi, Romania

d Departament de Química Inorgànica/Instituto de Ciencia Molecular, Facultat de Química de la Universitat de València, C/Catedrático José Beltrán 2, 46980 Paterna, València, Spain
E-mail: miguel.julve@uv.es

Abstract

The assembly reaction between the low-spin [CoII(dmphen)(CN)3]− metalloligand and the [MnIII(salen)(H2O)]+ complex cation yielded the one-dimensional compound {[MnIII(salen)(μ-NC)2CoII(dmphen)(CN)]·2H2O}n (1), which behaves as a ferrimagnetic chain, the intrachain magnetic coupling being J = −1.71(1) cm−1.

Graphical abstract: Synthesis, crystal structure and magnetic properties of a cyanide-bridged heterometallic {CoIIMnIII} chain

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Article information

DOI
https://doi.org/10.1039/C6DT04087J
Article type
Communication
Submitted
24 Oct 2016
Accepted
22 Nov 2016
First published
23 Nov 2016

Dalton Trans., 2017,46, 39-43

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Synthesis, crystal structure and magnetic properties of a cyanide-bridged heterometallic {CoIIMnIII} chain

M. Alexandru, D. Visinescu, S. Shova, F. Lloret and M. Julve, Dalton Trans., 2017, 46, 39 DOI: 10.1039/C6DT04087J

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