Issue 21, 2017
From the journal:

Dalton Transactions

Formation of high-molecular weight polyaminoborane by Fe hydride catalysed dehydrocoupling of methylamine borane†

F. Anke,a   D. Han,a   M. Klahn,a   A. Spannenberga  and  T. Beweries*a  

* Corresponding authors

a Leibniz-Institut für Katalyse an der Universität Rostock e.V., Albert-Einstein-Str. 29a, 18059 Rostock, Germany
E-mail: torsten.beweries@catalysis.de

Abstract

The complex [(PNHP)Fe(H)(CO)(HBH3)] (PNHP = HN(CH2CH2Pi-Pr2)2) serves as a catalyst precursor for the selective dehydrocoupling of methylamine borane at room temperature, tentatively via an off-metal polymerisation pathway.

Graphical abstract: Formation of high-molecular weight polyaminoborane by Fe hydride catalysed dehydrocoupling of methylamine borane

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Article information

DOI
https://doi.org/10.1039/C7DT01487B
Article type
Communication
Submitted
25 Apr 2017
Accepted
27 Apr 2017
First published
27 Apr 2017

Dalton Trans., 2017,46, 6843-6847

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Formation of high-molecular weight polyaminoborane by Fe hydride catalysed dehydrocoupling of methylamine borane

F. Anke, D. Han, M. Klahn, A. Spannenberg and T. Beweries, Dalton Trans., 2017, 46, 6843 DOI: 10.1039/C7DT01487B

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