KLi3Fe(C2O4)3: a perovskite-like compound with 1 : 3 ordering at both A and B sites

Wenjiao Yao; Yuan-Yuan Guo; Philip Lightfoot

doi:10.1039/C7DT03468G

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KLi₃Fe(C₂O₄)₃: a perovskite-like compound with 1 : 3 ordering at both A and B sites†

Wenjiao Yao,

^a Yuan-Yuan Guo^a and Philip Lightfoot*^a

Author affiliations

* Corresponding authors

^a School of Chemistry and EaStChem, University of St Andrews, St Andrews, Fife, UK
E-mail: pl@st-and.ac.uk

Abstract

KLi₃Fe(C₂O₄)₃ adopts a perovskite-like structure with 1 : 3 ordering of (Li,Fe) on the B-site and (K,vacancy) on the A-site; there are no previous examples of this type of cation ordering in conventional perovskites.

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Article information

DOI: https://doi.org/10.1039/C7DT03468G
Article type: Communication
Submitted: 15 Sep 2017
Accepted: 19 Sep 2017
First published: 20 Sep 2017

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Dalton Trans., 2017,46, 13349-13351

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KLi₃Fe(C₂O₄)₃: a perovskite-like compound with 1 : 3 ordering at both A and B sites

W. Yao, Y. Guo and P. Lightfoot, Dalton Trans., 2017, 46, 13349 DOI: 10.1039/C7DT03468G

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Dalton Transactions