Issue 37, 2018
From the journal:

Chemical Communications

Chiral separation and characterization of triazatruxene-based face-rotating polyhedra: the role of non-covalent facial interactions†

Pei Zhang,a   Xinchang Wang, ORCID logo a   Wei Xuan,a   Pixian Peng,a   Zhihao Li,a   Ruqiang Lu,a   Shuang Wu,a   Zhongqun Tian ORCID logo a  and  Xiaoyu Cao ORCID logo *a  

* Corresponding authors

a State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM) and Key Laboratory of Chemical Biology of Fujian Province, Xiamen University, Xiamen 361005, P. R. China
E-mail: xcao@xmu.edu.cn

Abstract

We constructed a series of novel chiral molecular face-rotating polyhedra (FRP) from two 10,15-dihydro-5H-diindolo[3,2-a:3′,2′-c]carbazole (triazatruxene) derivatives and trans-1,2-cyclohexane diamine, and investigated how facial interactions and the positions of substituents determine the diastereoselectivity and geometry of the final assemblies.

Graphical abstract: Chiral separation and characterization of triazatruxene-based face-rotating polyhedra: the role of non-covalent facial interactions

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Article information

DOI
https://doi.org/10.1039/C8CC02049C
Article type
Communication
Submitted
15 Mar 2018
Accepted
06 Apr 2018
First published
09 Apr 2018

Chem. Commun., 2018,54, 4685-4688

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Chiral separation and characterization of triazatruxene-based face-rotating polyhedra: the role of non-covalent facial interactions

P. Zhang, X. Wang, W. Xuan, P. Peng, Z. Li, R. Lu, S. Wu, Z. Tian and X. Cao, Chem. Commun., 2018, 54, 4685 DOI: 10.1039/C8CC02049C

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