Electronic effects of the Bernal stacking of graphite on self-assembled aromatic adsorbates

Nataliya Kalashnyk; Maud Jaouen; Céline Fiorini-Debuisschert; Ludovic Douillard; André-Jean Attias; Fabrice Charra

doi:10.1039/C8CC05806G

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Electronic effects of the Bernal stacking of graphite on self-assembled aromatic adsorbates†

Nataliya Kalashnyk,

‡^ab Maud Jaouen,^a Céline Fiorini-Debuisschert,

^a Ludovic Douillard,

^a André-Jean Attias

*^bc and Fabrice Charra

*^a

Author affiliations

* Corresponding authors

^a SPEC, CEA, CNRS, UMR 3680, Université Paris-Saclay, CEA Saclay, 91191 Gif-sur-Yvette Cedex, France
E-mail: fabrice.charra@cea.fr

^b Institut Parisien de Chimie Moléculaire, UMR CNRS 8232, Sorbonne Universités, 4 Place Jussieu, 75252 Paris Cedex, France
E-mail: andre-jean.attias@sorbonne-universite.fr

^c UMI Building Blocks for Future Electronics, CNRS - Sorbonne Université, Yonsei University, Ewha Womans University, 50 Yonsei-ro Seodaemun-gu, Seoul, Korea

Abstract

We compare by Scanning Tunneling Microscopy (STM) self-organized honeycomb monolayers of aromatic molecules formed either on graphite or on graphene. A differential contrast between the adsorption sites observed exclusively on graphite evidences the electronic effects of the symmetry breaking by the staggered atomic layers forming this substrate.

This article is part of the themed collection: Scanning probe frontiers in molecular 2D-architecture world

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Article information

DOI: https://doi.org/10.1039/C8CC05806G
Article type: Communication
Submitted: 17 Jul 2018
Accepted: 01 Aug 2018
First published: 02 Aug 2018

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Chem. Commun., 2018,54, 9607-9610

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Electronic effects of the Bernal stacking of graphite on self-assembled aromatic adsorbates

N. Kalashnyk, M. Jaouen, C. Fiorini-Debuisschert, L. Douillard, A. Attias and F. Charra, Chem. Commun., 2018, 54, 9607 DOI: 10.1039/C8CC05806G

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Chemical Communications

Electronic effects of the Bernal stacking of graphite on self-assembled aromatic adsorbates†

Abstract

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Electronic effects of the Bernal stacking of graphite on self-assembled aromatic adsorbates

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