Issue 43, 2018
From the journal:

Dalton Transactions

Water stable oxalate-based coordination polymers with in situ generated cyclic dipeptides showing high proton conductivity†

Jingyu Shi,a   Jing Li,a   Hongmei Zeng,a   Guohong Zou, ORCID logo *a   Qinghua Zhang ORCID logo b  and  Zhien Lin ORCID logo *a  

* Corresponding authors

a College of Chemistry, Sichuan University, Chengdu 610064, P. R. China
E-mail: zough@scu.edu.cn, zhienlin@scu.edu.cn

b Institute of Chemical Materials, China Academy of Engineering Physics, Mianyang 621900, P. R. China

Abstract

Presented here are two water stable oxalate-based coordination polymers with in situ generated cyclic dipeptides, namely, (C12H16N6O2)[Zn2(C2O4)3] (SCU-63) and Mn(C2O4)(C12H14N6O2) (SCU-66). SCU-63 has a honeycomb-like layer intercalated with protonated cyclic dipeptide cations. SCU-66 has a diamondoid framework containing cyclic dipeptide ligands. The two compounds show high proton conductivity on the order of 10−3 S cm−1 at 85 °C under 98% relative humidity.

Graphical abstract: Water stable oxalate-based coordination polymers with in situ generated cyclic dipeptides showing high proton conductivity

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Article information

DOI
https://doi.org/10.1039/C8DT03659D
Article type
Communication
Submitted
10 Sep 2018
Accepted
02 Oct 2018
First published
03 Oct 2018

Dalton Trans., 2018,47, 15288-15292

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Water stable oxalate-based coordination polymers with in situ generated cyclic dipeptides showing high proton conductivity

J. Shi, J. Li, H. Zeng, G. Zou, Q. Zhang and Z. Lin, Dalton Trans., 2018, 47, 15288 DOI: 10.1039/C8DT03659D

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