The reactivity of alkali metal capped Ce(IV) imido compounds [M(DME)2][Ce![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
NArF(TriNOx)] (1-M with M = K, Rb, Cs and ArF = 3,5-bis(trifluoromethyl)phenyl) with CO2 and organic isocyanates has been evaluated. 1-Cs reacted with CO2 to yield an organocarbamate complex. Reaction of 1-K and 1-Rb with organic isocyanates yielded organoureate Ce(IV) complexes.
E. N. Lapsheva, T. Cheisson, C. Álvarez Lamsfus, P. J. Carroll, M. R. Gau, L. Maron and E. J. Schelter, Chem. Commun., 2020, 56, 4781 DOI: 10.1039/C9CC10052K
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