Issue 30, 2020
From the journal:

Chemical Communications

Diphenyl-1-pyrenylphosphine: photo-triggered AIE/ACQ transition with remarkable third-order nonlinear optical signal change†

Chang Xing,‡a   Jianxun Liu,‡a   Fang Chen,a   Yuanyuan Li, ORCID logo *b   Changjian Lv,a   Qiuchen Peng,ab   Hongwei Hou ORCID logo *a  and  Kai Li ORCID logo *a  

* Corresponding authors

a Green Catalysis Center, and College of Chemistry, Zhengzhou University, Henan 450001, P. R. China
E-mail: likai@zzu.edu.cn

b School of Chemistry and Chemical Engineering, Henan University of Technology, Henan, P. R. China
E-mail: yuanyuanli@haut.edu.cn

Abstract

A propeller-like pyrene derivative of diphenyl-1-pyrenylphosphine (DPPP) is designed and synthesized. DPPP exhibits a unique photo-triggered AIE/ACQ transition with a remarkable third-order nonlinear optical signal change, which is proved to originate from the photo-induced oxidation of a phosphorus atom.

Graphical abstract: Diphenyl-1-pyrenylphosphine: photo-triggered AIE/ACQ transition with remarkable third-order nonlinear optical signal change

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Article information

DOI
https://doi.org/10.1039/D0CC01031F
Article type
Communication
Submitted
09 Feb 2020
Accepted
09 Mar 2020
First published
09 Mar 2020

Chem. Commun., 2020,56, 4220-4223

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Diphenyl-1-pyrenylphosphine: photo-triggered AIE/ACQ transition with remarkable third-order nonlinear optical signal change

C. Xing, J. Liu, F. Chen, Y. Li, C. Lv, Q. Peng, H. Hou and K. Li, Chem. Commun., 2020, 56, 4220 DOI: 10.1039/D0CC01031F

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