Comment on “Investigation of Zr(IV) and 89Zr(IV) complexation with hydroxamates: progress towards designing a better chelator than desferrioxamine B for immuno-PET imaging” by F. Guérard, Y.-S. Lee, R. Tripier, L. P. Szajek, J. R. Deschamps and M. W. Brechbiel, Chem. Commun., 2013, 49, 1002

Antonio Bianchi; Matteo Savastano

doi:10.1039/D0CC01189D

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Comment on “Investigation of Zr(iv) and ⁸⁹Zr(iv) complexation with hydroxamates: progress towards designing a better chelator than desferrioxamine B for immuno-PET imaging” by F. Guérard, Y.-S. Lee, R. Tripier, L. P. Szajek, J. R. Deschamps and M. W. Brechbiel, Chem. Commun., 2013, 49, 1002†

Antonio Bianchi

*^a and Matteo Savastano

*^a

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* Corresponding authors

^a Department of Chemistry “Ugo Schiff”, University of Florence, Italy
E-mail: antonio.bianchi@unifi.it, matteo.savastano@unifi.it

Abstract

An alternative analysis of the complexes formed by Zr(IV) with acetohydroxamate shows that, in comparison with the results reported in the title article, a more complicated complexation model is found, the stability constants of the common complexes are considerably different and complexation of Zr(IV) does not show any unusual behaviour.

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Article information

DOI: https://doi.org/10.1039/D0CC01189D
Article type: Comment
Submitted: 14 Feb 2020
Accepted: 10 Sep 2020
First published: 18 Sep 2020

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Chem. Commun., 2020,56, 12664-12666

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Comment on “Investigation of Zr(IV) and ⁸⁹Zr(IV) complexation with hydroxamates: progress towards designing a better chelator than desferrioxamine B for immuno-PET imaging” by F. Guérard, Y.-S. Lee, R. Tripier, L. P. Szajek, J. R. Deschamps and M. W. Brechbiel, Chem. Commun., 2013, 49, 1002

A. Bianchi and M. Savastano, Chem. Commun., 2020, 56, 12664 DOI: 10.1039/D0CC01189D

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