Memory devices based on novel alkyl viologen halobismuthate(III) complexes

Dolgor D. Dashitsyrenova; Sergey A. Adonin; Igor D. Gorokh; Olga A. Kraevaya; Alina V. Pavlova; Pavel A. Abramov; Lyubov A. Frolova; Maxim N. Sokolov; Vladimir P. Fedin; Pavel A. Troshin

doi:10.1039/D0CC03732J

Memory devices based on novel alkyl viologen halobismuthate(iii) complexes†

Dolgor D. Dashitsyrenova,^a Sergey A. Adonin,

*^bc Igor D. Gorokh,^bd Olga A. Kraevaya,

^ad Alina V. Pavlova,^e Pavel A. Abramov,

^b Lyubov A. Frolova,^ad Maxim N. Sokolov,

^b Vladimir P. Fedin^b and Pavel A. Troshin

^ad

Author affiliations

* Corresponding authors

^a Institute for Problems of Chemical Physics RAS, Semenov Prospect 1, Chernogolovka, Russia

^b Nikolaev Institute of Inorganic Chemistry SB RAS, Lavrentieva St. 3, Novosibirsk, Russia
E-mail: adonin@niic.nsc.ru

^c South Ural State University, Lenina St. 76, 454080 Chelyabinsk, Russia

^d Skolkovo Institute of Science and Technology, Nobel St. 3, Moscow, Russia

^e State Research Center Burnasyan Federal Medical Biophysical Center of Federal Medical and Biological Agency, Zhivopisnaya St. 46, Moscow, Russia

Abstract

Four novel halobismuthate(III) complexes with alkyl viologen cations: (R₂Viol)₂[Bi₂X₁₀] (R = n-butyl, n-pentyl, X = Cl, Br) have been synthesized. Both chloride complexes revealed photochromic behavior and were successfully utilized for the fabrication of OFET-based memory devices with high switching coefficients and good write–read–erase cycling stability.

Chemical Communications

Memory devices based on novel alkyl viologen halobismuthate(iii) complexes†

Abstract

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Memory devices based on novel alkyl viologen halobismuthate(III) complexes

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