The reaction between MB-DIPY sodium salts and Ag(I) ions results in the formation of unprecedented MB-DIPY2Ag2 dimers in both solution and the solid state. These dimers have a short Ag–Ag contact (∼2.9 Å) and orthogonal twist in each of the MB-DIPY chromophores. The electronic structure of the unique dimers was probed by spectroscopic and theoretical methods.
Y. V. Zatsikha, L. I. Shamova, T. S. Blesener, D. E. Herbert and V. N. Nemykin, Dalton Trans., 2020, 49, 5034 DOI: 10.1039/D0DT00927J
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