Metal–metal bond formation of triplatinum cores with a silver(I) ion affording a heptanuclear cluster bearing four Pt–Ag bonds

Natsuki Yabune; Hiroshi Nakajima; Takanori Nishioka

doi:10.1039/D0DT01227K

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Metal–metal bond formation of triplatinum cores with a silver(i) ion affording a heptanuclear cluster bearing four Pt–Ag bonds†

Natsuki Yabune,^a Hiroshi Nakajima

^a and Takanori Nishioka

*^a

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* Corresponding authors

^a Department of Chemistry, Graduate School of Science, Osaka City University, Osaka 558-8585, Japan
E-mail: nishioka@sci.osaka-cu.ac.jp

Abstract

An N-heterocyclic carbene triplatinum complex with two triply bridging sulfide ligands reacts with a silver(I) salt and affords a heptanuclear complex. X-ray crystallographic analysis revealed that a silver(I) ion connects two triplatinum complexes with one of the three Pt–Pt bonds of each triplatinum unit.

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DOI: https://doi.org/10.1039/D0DT01227K
Article type: Communication
Submitted: 02 Apr 2020
Accepted: 27 Apr 2020
First published: 28 Apr 2020

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Dalton Trans., 2020,49, 7680-7683

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Metal–metal bond formation of triplatinum cores with a silver(I) ion affording a heptanuclear cluster bearing four Pt–Ag bonds

N. Yabune, H. Nakajima and T. Nishioka, Dalton Trans., 2020, 49, 7680 DOI: 10.1039/D0DT01227K

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Metal–metal bond formation of triplatinum cores with a silver(i) ion affording a heptanuclear cluster bearing four Pt–Ag bonds†

Abstract

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Metal–metal bond formation of triplatinum cores with a silver(I) ion affording a heptanuclear cluster bearing four Pt–Ag bonds

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