An organophosphorus-mediated cross-Rauhut–Currier/Wittig domino reaction for the efficient synthesis of trisubstituted cyclopentenes

Ya-Qiong Li; Guo-Dong Xu; Zhi-Zhen Huang

doi:10.1039/D1OB00150G

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An organophosphorus-mediated cross-Rauhut–Currier/Wittig domino reaction for the efficient synthesis of trisubstituted cyclopentenes†

Ya-Qiong Li,^ab Guo-Dong Xu^a and Zhi-Zhen Huang

*^a

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* Corresponding authors

^a Department of Chemistry, Zhejiang University, Hangzhou 310058, P.R. China
E-mail: huangzhizhen@zju.edu.cn

^b School of Chemistry and Chemical Engineering, Yangtze Normal University, Chongqing, P.R. China

Abstract

An efficient organophosphorus-mediated cross-Rauhut–Currier/Wittig domino reaction of vinyl ketones with chalcones has been developed for the synthesis of trisubstituted cyclopentenes. The new synthetic method has the advantages of mild reaction conditions, high efficiency, environmental friendliness and satisfactory yields.

This article is part of the themed collection: Synthetic methodology in OBC

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DOI: https://doi.org/10.1039/D1OB00150G
Article type: Paper
Submitted: 26 Jan 2021
Accepted: 24 Feb 2021
First published: 03 Mar 2021

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Org. Biomol. Chem., 2021,19, 2487-2491

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An organophosphorus-mediated cross-Rauhut–Currier/Wittig domino reaction for the efficient synthesis of trisubstituted cyclopentenes

Y. Li, G. Xu and Z. Huang, Org. Biomol. Chem., 2021, 19, 2487 DOI: 10.1039/D1OB00150G

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Organic & Biomolecular Chemistry

An organophosphorus-mediated cross-Rauhut–Currier/Wittig domino reaction for the efficient synthesis of trisubstituted cyclopentenes†

Abstract

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An organophosphorus-mediated cross-Rauhut–Currier/Wittig domino reaction for the efficient synthesis of trisubstituted cyclopentenes

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