A photoredox approach enabling one-step synthesis of oxazetidines with a free –NH group via the combined use of alkyne, thiophenol, and azide has been reported. The synthesized oxazetidine with the free –NH group was stable enough for various late-stage transformations such as methylation, acetylation, tosylation, and ring-opening reaction to afford synthetically useful α-aminoketones.
M. A. Ganie, M. Bhat, M. A. Rizvi, S. Raheem and B. A. Shah, Chem. Commun., 2022, 58, 8508 DOI: 10.1039/D2CC02892A
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