Issue 9, 2023

Manganese(iii) porphyrin-catalyzed regioselective dual functionalization of C(sp3)–H bonds: the transformation of arylalkanes to 1,4-diketones

Abstract

The first, direct way from arylalkanes to 1,4-dicarbonyl compounds has been shown. It makes obtaining these useful products more accessible and cheaper. Our method is based on a one-pot reaction with excellent regioselectivity, mild conditions, and water as the main solvent. A plausible reaction mechanism has also been proposed.

Graphical abstract: Manganese(iii) porphyrin-catalyzed regioselective dual functionalization of C(sp3)–H bonds: the transformation of arylalkanes to 1,4-diketones

Supplementary files

Article information

Article type
Communication
Submitted
12 Nov 2022
Accepted
21 Nov 2022
First published
03 Jan 2023
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2023,59, 1149-1152

Manganese(III) porphyrin-catalyzed regioselective dual functionalization of C(sp3)–H bonds: the transformation of arylalkanes to 1,4-diketones

J. Sukiennik, A. Pranowo, S. Domański and K. Hurej, Chem. Commun., 2023, 59, 1149 DOI: 10.1039/D2CC06126K

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