Issue 68, 2023
From the journal:

Chemical Communications

Reversible structural transformations and color-tunable emissions in organic manganese halides†

Yu-Hang Liu,ab   Yi-Fan Wu,a   Li-Juan Feng,a   Rui-Rui Zhao,a   Shan-Xiao Wang,a   Ming-Ming Zhang,a   Dan-Yang Wang,a   Xiang-Wen Kong*a  and  Xiao-Wu Lei ORCID logo *a  

* Corresponding authors

a School of Chemistry, Chemical Engineer and Materials, Jining University, Qufu, Shandong, P. R. China
E-mail: kxw2021@126.com, xwlei_jnu@163.com

b School of Chemistry and Chemical Engineering, Qufu Normal University, Qufu, Shandong, P. R. China

Abstract

Herein, we for the first time report a reversible conversion between green-emissive [DMPZ]MnCl4 and red-emissive [DMPZ]4(MnCl6)(MnCl4)2·(H2O)2 (DMPZ = 1,4-dimethylpiperazine) using kinetic and thermodynamic controlling strategies. Significantly, the synchronous structural and emission transformations in single-component organic manganese halides with adjustable emission colors are highlighted.

Graphical abstract: Reversible structural transformations and color-tunable emissions in organic manganese halides

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Article information

DOI
https://doi.org/10.1039/D3CC02093B
Article type
Communication
Submitted
29 Apr 2023
Accepted
27 Jul 2023
First published
27 Jul 2023

Chem. Commun., 2023,59, 10267-10270

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Reversible structural transformations and color-tunable emissions in organic manganese halides

Y. Liu, Y. Wu, L. Feng, R. Zhao, S. Wang, M. Zhang, D. Wang, X. Kong and X. Lei, Chem. Commun., 2023, 59, 10267 DOI: 10.1039/D3CC02093B

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