Issue 34, 2023

Spodium, halogen and hydrogen bonds in the reactivity of bis(2,4-bis(trichloromethyl)-1,3,5-triazapentadienato)-Zn(ii)

Abstract

The role of noncovalent interactions (spodium, halogen and hydrogen bonds) in the reaction of [Zn{NH[double bond, length as m-dash]C(CCl3)NC(CCl3)[double bond, length as m-dash]NH}2] with acetone, pyrazole, 4,4′-bipyridine and Cu(acetylacetonate)2 is reported. Depending on the reactants, different types of organic, coordination and supramolecular compounds were isolated, and various types of noncovalent interactions were disclosed.

Graphical abstract: Spodium, halogen and hydrogen bonds in the reactivity of bis(2,4-bis(trichloromethyl)-1,3,5-triazapentadienato)-Zn(ii)

Supplementary files

Article information

Article type
Communication
Submitted
27 Jun 2023
Accepted
31 Jul 2023
First published
01 Aug 2023

New J. Chem., 2023,47, 15856-15861

Spodium, halogen and hydrogen bonds in the reactivity of bis(2,4-bis(trichloromethyl)-1,3,5-triazapentadienato)-Zn(II)

I. M. Garazade, A. V. Gurbanov, R. M. Gomila, A. Frontera, A. V. M. Nunes, K. T. Mahmudov and A. J. L. Pombeiro, New J. Chem., 2023, 47, 15856 DOI: 10.1039/D3NJ02994H

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