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Abstract | Cited by

Triflic acids/silanes as cooperative reductants enable the convenient transformation of C[double bond, length as m-dash]O bonds through a multistep reaction pathway in one pot. Electrolysis of the acidic reaction mixture significantly improved carbonyl reduction and thus facilitated the generation of benzyl carbocations, which show high reactivity towards electron-rich heteroarenes for C–C bond formation.

Graphical abstract: Electrochemically enhanced deoxygenative cross-coupling of aryl ketones with heteroarenes through in situ generated benzyl carbocations

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