Herein, we disclose a new photoredox-catalysed strategy to access gem-difluoroallylarenes from α-trifluoromethylalkenes with sterically hindered primary amines via C–N and C–F bond activation. This deaminative and defluorinative allylation is generally compatible with diverse functional groups and sterically hindered α-3° and 2° primary amines.
G. Zhang, L. Wang, L. Cui, P. Gao and F. Chen, Org. Biomol. Chem., 2023, 21, 294 DOI: 10.1039/D2OB02114E
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