Nonequilibrium structure formation in electrohydrodynamic emulsions

Abstract

Application of an electric field across the interface of two fluids with low, but non-zero, conductivities gives rise to a sustained electrohydrodynamic (EHD) fluid flow. In the presence of neighboring drops, drops interact via the EHD flows of their neighbors, as well as through a dielectrophoretic (DEP) force, a consequence of drops encountering disturbance electric fields around their neighbors. We explore the collective dynamics of emulsions with drops undergoing EHD and DEP interactions. The interplay between EHD and DEP results in a rich set of emergent behaviors. We simulate the collective behavior of large numbers of drops; in two dimensions, where drops are confined to a plane; and three dimensions. In monodisperse emulsions, drops in two dimensions cluster or crystallize depending on the relative strengths of EHD and DEP, and form spaced clusters when EHD and DEP balance. In three dimensions, chain formation observed under DEP alone is suppressed by EHD, and lost entirely when EHD dominates. When a second population of drops are introduced, such that the electrical conductivity, permittivity, or viscosity are different from the first population of drops, the interaction between the drops becomes non-reciprocal, an apparent violation of Newton's Third Law. The breadth of consequences due to these non-reciprocal interactions are vast: we show selected cases in two dimensions, where drops cluster into active dimers, trimers, and larger clusters that continue to translate and rotate over long timescales; and three dimensions, where drops form stratified chains, or combine into a single dynamic sheet.