Influence of a neighbouring Cu centre on electro- and photocatalytic CO2 reduction by Fe-Mabiq

Kerstin Rickmeyer; Matthias Huber; Corinna R. Hess

doi:10.1039/D3CC04777F

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Influence of a neighbouring Cu centre on electro- and photocatalytic CO₂ reduction by Fe-Mabiq†

Kerstin Rickmeyer,^ab Matthias Huber^ab and Corinna R. Hess

*^ab

Author affiliations

* Corresponding authors

^a Department of Chemistry and Catalysis Research Center (CRC), Technical University of Munich, Garching 85748, Germany

^b Faculty of Chemistry and Pharmacy, University of Regensburg, Regensburg 93053, Germany
E-mail: corinna.hess@ur.de

Abstract

Electrocatalytic and photocatalytic CO₂ reduction by a heterobimetallic Cu/Fe–Mabiq complex were examined and compared to the monometallic [Fe(Mabiq)]⁺. The neighbouring Cu–Xantphos unit leads to marked changes in the electrocatalytic mechanism and enhanced photocatalytic performance.

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Article information

DOI: https://doi.org/10.1039/D3CC04777F
Article type: Communication
Submitted: 26 Sep 2023
Accepted: 12 Dec 2023
First published: 14 Dec 2023

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Chem. Commun., 2024,60, 819-822

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Influence of a neighbouring Cu centre on electro- and photocatalytic CO₂ reduction by Fe-Mabiq

K. Rickmeyer, M. Huber and C. R. Hess, Chem. Commun., 2024, 60, 819 DOI: 10.1039/D3CC04777F

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